Why is Polycarboxylate Superplasticizer Modified?

The China Securities New Energy Vehicle index rose as much as 4.1 percent after a strong rally in lithium-ion shares on the Chinese stock market. Brokerages said lithium enterprises would usher in marginal expectations, and currently, it may be the best time to layout power/energy storage lithium batteries.

According to a securities research report, the price of lithium carbonate in the upstream resource end continues to hit a new high, which reflects the shortage of lithium mineral resources, and lithium has become one of the core elements of the development of the lithium electricity industry. In 2022, global demand for lithium carbonate continues to grow strongly, while the supply-side growth is relatively limited. And, because related mining enterprises experienced the last lithium down cycle, they would expand concrete superplasticizer are expected to rise.

Concrete water reducing agent is one of the technical ways to reduce the cement dosage, improve the utilization rate of industrial waste residue, and realize the durability and high performance of concrete. It is also one of the key materials for the development of concrete to high-tech field. And polycarboxylate type water reducing agent (PC) has become a kind of efficient water reducing agent with the most rapid development and the largest market potential because of its low toxicity and environmental protection characteristics.  Compared with the traditional admixtures, the admixtures have become the focus of worldwide research and development because of their excellent dispersibility and slump retention ability. 

Although polycarboxylate water reducing admixture outstanding performance and ability to maintain good slump has been widely recognized, but because of the existence of mineral composition, cement fineness, cement plaster form and content, admixture adding amount, and the mixing process of concrete mixture ratio, water has a very high sensitivity, seriously affected the existing products are widely used in engineering. 

What is Polycarboxylate Series Water Reducing Agent?

Polycarboxylate superplasticizer is a kind of surfactant containing carboxylic graft copolymer. Its molecules are comb shaped and have high steric hindrance effect. As the third generation of high-performance water reducing agent after lignosulfonate ordinary water reducing agent, naphthalene series aliphatic group, sulfamate and other high-efficiency water reducing agent. 

It is because of molecular structure design performance is good, high reduce water, low admixture amount, keep slump good, enhance good, contain alkali amount is low, to set time influence is small, and most cement compatibility is good and pollution-free and other advantages are regarded as the most development potential of water reducing agent variety.

Polycarboxylate superplasticizer is a new high-efficiency superplasticizer developed and produced successfully after naphthalene, melamine, aliphatic and sulfamate superplasticizer.  In its content is low (solid content 0.15% - 0.25%) can produce an ideal water reducing and enhanced effect, less impact on the setting time of concrete and slump retention, adaptability to cement and admixture is relatively good, a smaller influence on drying shrinkage of concrete (usually not too much increase drying shrinkage), without the use of formaldehyde in the process of production and does not discharge waste liquor, SO  The low content of 42- and Cl- has been praised by researchers and some users since the beginning. 

Why should Polycarboxylate Superplasticizer be Modified? 

Compared with naphthalene series high efficient water reducing agent, such as, although poly carboxylic acid water reducing agent in the reduction of water conservation slump has obvious advantages in aspects of environmental protection, but there are some technical problems in the practical engineering application, such as water reducing effect of concrete raw materials, mixing ratio, water reducing agent dosage dependence is very big, fresh concrete performance is sensitive to water consumption, easy preparation of large liquidity segregation layer. Poor compatibility with other water-reducing agents and modified components and poor product stability greatly restrict the wide application and development of polycarboxylate water-reducing agents. 

In order to overcome the technical defects in the application of polycarboxylate water-reducing agent, or to improve some or some properties of concrete (workability, slump retention, reduction of bleeding, improvement of early strength, low shrinkage, etc.), it is necessary to modify the concrete. 

In practice, the commonly used modification methods include synthetic technology and compound technology. Compared with the synthetic process, the compound method has the advantages of simple operation and low cost, so it is widely used in practical applications. Polycarboxylate series compound technology, is the polycarboxylate series water-reducing agent and other components (such as slow coagulation, defoamy, air induction, early strength and other components) according to a certain proportion of the combination compound, in order to achieve the coordination of the superposition of each component.

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The United States urges the U.N. Security Council to impose additional sanctions on North Korea in response to its latest ballistic missile launch, including a ban on tobacco and oil exports to North Korea and a blacklist of the Lazarus hacking group.  

The United States circulated the draft to the 15 members of the Security Council this week. It was not immediately clear if or when a vote would take place. A resolution requires nine "yes" votes and no vetoes from Russia, China, France, Britain, or the United States.  

Russia and China have already voiced opposition to tightening sanctions in response to Pyongyang's launch of an intercontinental ballistic missile last month -- the first since 2017.  

U.S. and South Korean officials and analysts also say there are growing indications that North Korea may soon conduct its first nuclear weapons test since 2017, too.  

The U.S. -drafted U.N. resolution would expand the ban on ballistic missile launches to include cruise missiles or "any other delivery system capable of delivering a nuclear weapon."  

The deal would halve crude oil exports to North Korea to 2 million barrels a year and refined oil exports to 250,000 barrels a year. The resolution also seeks to ban North Korea's export of "fossil fuels, mineral oils, and their distilled concrete superplasticizer are estimated to be influenced by international political situation changes.

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